06. Alfredo di Stéfano – Goals: 227
Alfredo di Stéfano was a retired soccer player of Argentine football team and also worked as coach of the team. He is considered as one of the best soccer players of all time. During his career, he mainly played for the club, Real Madrid. He played very vital role in the performance of the club, specifically during the 1950s. In his La Liga career, he scored 227 goals and earned for him the fifth position in the list of the highest goal scorers in La Liga.
See also: Top 10 Best teams in FIFA history